Friday's clash at the Municipal Stadium Wroclaw will be the first time both countries will be meeting at the worldwide level.
Later in the day, the team announced the arrival of Odion Ighalo, Ogenyi Onazi, Uche Agbo and Ahmed Musa to the camp.
They join other players presently in camp Leon Balogun, William Troost Ekong, Ola Aina, Alex Iwobi, Brian Idowu and Tyronne Ebuehi.
This was confirmed by the Super Eagles verified Twitter handle on Tuesday.
Voting stations are opening across Russian Federation as Putin seeks a fourth term
They are facing unusually intense pressure to vote, to grant him a convincing new mandate to pursue his nationalist strategy. In Moscow alone, authorities are spending 50 million ($870,000) on balloons and festive decorations at polling stations.
Reports on Monday say Invited players have started reporting to the Radisson Blu Hotel camp set up by the Nigeria football federation.
The Super Eagles will welcome the Democratic Republic of Congo on May, 25, as a sent forth match, then trade tackles with England and the Czech Republic on June 2 and 5 before the competition kicks off proper.
The 22-year-old will issue a fast route visa to make it to London for the second friendly game against Serbia four days after the clash with Poland.Ajayi won the league, cup and super cup since joining Al Ahly.
The Super Eagles will square up in Group D against Argentina, Croatia, and Iceland when the soccer fiesta begins in June.